2-(Methylsulfanyl)cyclododecanone tosylhydrazone
نویسندگان
چکیده
The title compound, C(20)H(32)N(2)O(2)S(2), has been synthesized by the reaction of α-methyl-sulfanylcyclo-dodeca-none and p-toluene-sulfonyl-hydrazine. In the crystal structure, the conformation of the non-benzenoid ring is [3333] and the methyl-sulfanyl group is in the α-side exo position. The mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds.
منابع مشابه
(5′′E)-1′′-Benzyl-1′-methyl-5′′-[4-(methylsulfanyl)benzylidene]-4′-[4-(methylsulfanyl)phenyl]dispiro[indoline-3,2′-pyrrolidine-3′,3′′-piperidine]-2,4′′-dione dichloromethane solvate
In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C-H⋯O intra-molecular contacts occur. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N inter-actions. The dichloro-methane solvent mol-ecule is disordered over ...
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In the title compound, C(15)H(15)N(5)O(2)S(2), the phenyl rings make dihedral angles of 4.03 (4) and 9.77 (5)° with the plane defined by the central N-N-C-N-N atoms (r.m.s. deviation = 0.010 Å). The C-S-C-C torsion angles of the methyl-sulfanyl groups with their respective phenyl rings are -7.47 (13) and -72.07 (13)°. The shortest centroid-centroid distance of 3.707 Å occurs between the two π-s...
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